2024
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Pradhan, P.; Moktan, S.; Halder, Biswas, A.; Das, A.; Lenka, R.; Bhattacharya, K.; Kancharla, P. K.* “Triple Role of Proton Sponge (DMAN) in the Palladium-Catalyzed Direct Stereoselective Synthesis of C-Aryl Glycosides from Glycals”Org. Lett. 2024, ASAP.
![](https://static.wixstatic.com/media/a1862a_47d601ebf5a34533af4e90dba2621f95~mv2.png/v1/fill/w_894,h_209,al_c,q_85,usm_0.66_1.00_0.01,enc_auto/a1862a_47d601ebf5a34533af4e90dba2621f95~mv2.png)
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Addanki, R. B.; Moktan, S.; Halder, S. H.; Sharma, M.; Sarmah, B. K.; Bhattacharya, K.; Kancharla, P. K.* “Exploiting the Strained Ion-Pair Interactions of Sterically Hindered Pyridinium Salts Toward SN2 Glycosylation of Glycosyl Trichloroacetimidates” J. Org. Chem. 2024, ASAP.
![TOC_edited.jpg](https://static.wixstatic.com/media/a1862a_c32f955e166c42819f09b4c4a4ec0659~mv2.jpg/v1/fill/w_894,h_305,al_c,q_80,usm_0.66_1.00_0.01,enc_auto/TOC_edited.jpg)
2023
![untitled.tif](https://static.wixstatic.com/media/a1862a_32c53f046e904a73a323223baa33302c~mv2.png/v1/fill/w_67,h_31,al_c,q_85,usm_0.66_1.00_0.01,blur_2,enc_auto/untitled_tif.png)
![graphicalabstract.tif](https://static.wixstatic.com/media/a1862a_91013b4c873b4629bbb236f57b4d8de2~mv2.png/v1/crop/x_0,y_0,w_2929,h_618/fill/w_89,h_19,al_c,q_85,usm_0.66_1.00_0.01,blur_2,enc_auto/graphicalabstract_tif.png)
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Halder, S. H.; Addanki, R. B.; Kancharla, P. K.* “Regio- and Stereoselective C-Glycosylation of Indoles Using o-[1-(p-MeO-Phenyl)vinyl]benzoates (PMPVB) as Glycosyl Donors under Brønsted Acid Catalysis” J. Org. Chem. 2023, 88, 3, 1844-1854, ASAP.
![Abstract_edited.jpg](https://static.wixstatic.com/media/a1862a_9eff628499f740519eb9d377bf72dbe7~mv2.jpg/v1/fill/w_113,h_46,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/Abstract_edited.jpg)
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Mukherji, A.; Mahendra, K. V. Rotta; Kancharla, P. K.* “Influence of Various Silyl Protecting Groups on Stereoselective 2-Deoxyrhamnosylation” J. Org. Chem. 2023, 88, 245-260.
![Abstract.tif](https://static.wixstatic.com/media/a1862a_54e551f56eca490995b32434c0e9d4f5~mv2.png/v1/fill/w_63,h_63,al_c,q_85,usm_0.66_1.00_0.01,blur_2,enc_auto/Abstract_tif.png)
2022
![Picture1.jpg](https://static.wixstatic.com/media/a1862a_fcb17de6901b4ac7960ed38b76c0517b~mv2.jpg/v1/crop/x_2,y_0,w_1387,h_364/fill/w_134,h_35,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/Picture1.jpg)
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Halder, S. H.; Addanki, R. B.; Moktan, S.; Kancharla, P. K.* “Glycosyl Ortho-[1-(p-MeOPhenyl)Vinyl]Benzoates (PMPVB) as Easily Accessible, Stable, and Reactive Glycosyl Donors for O-, S- and C-glycosylations Under Brønsted Acid Catalysis” J. Org. Chem. 2022, ASAP Link.
![TOCtif.tif](https://static.wixstatic.com/media/a1862a_ae2aa1e30bcf4865b487e6bc3a2a811c~mv2.png/v1/crop/x_0,y_0,w_2078,h_612/fill/w_73,h_21,al_c,q_85,usm_0.66_1.00_0.01,blur_2,enc_auto/TOCtif_tif.png)
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Addanki, R. B.; Halder, S. H.; Kancharla, P. K.* “TfO–···H–O–H Interaction-Assisted Generation of a Silicon Cation from Allylsilanes: Access to Phenylallyl Ferrier Glycosides from Glycals” Org. Lett. 2022, 24, 7, 1465-1470 Link.
![ol2c00062_0011.jpeg](https://static.wixstatic.com/media/a1862a_8f905e336f3f44f8946bfd26195f7a6f~mv2.jpeg/v1/fill/w_127,h_39,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/ol2c00062_0011.jpeg)
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Halder, S. H.; Addanki, R. B.; Kancharla, P. K.* “Catalytic stereoselective synthesis of 2-deoxy α-glycosides using glycosyl ortho-[1-(p-MeOPhenyl)Vinyl]Benzoate (PMPVB) donors” Org. & Biomol. Chem. 2022, ASAP.. Link.
![TOC-OBC.jpg](https://static.wixstatic.com/media/a1862a_82106775814246829d8ba51b005e0952~mv2.jpg/v1/fill/w_132,h_43,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/TOC-OBC.jpg)
2021
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Mukherji, A.; Addanki, R. B.; Halder, S. H.; Kancharla, P. K.* “Sterically Strained Brønsted Pair Catalysis by Bulky Pyridinium Salts: Direct Stereoselective Synthesis of 2-Deoxy and 2,6-Dideoxy-β-thioglycosides from Glycals” J. Org. Chem. 2021, 86, 17226-17243. Link.
![TOC.tif](https://static.wixstatic.com/media/a1862a_7caaaeaa6bdb488895a69390b223ec46~mv2.png/v1/crop/x_0,y_44,w_2729,h_587/fill/w_86,h_18,al_c,q_85,usm_0.66_1.00_0.01,blur_2,enc_auto/TOC_tif.png)
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Priyanka Adhikari, Dipanjan Bhattacharyya, Sekhar Nandi, Pavan K. Kancharla and Animesh Das* “Reductive Alkylation of Quinolines to N-Alkyl Tetrahydroquinolines Catalyzed by Arylboronic Acid” Org. Lett. 2021, 23, 2437-2442. Link.
![AD-Org%20lett_edited.jpg](https://static.wixstatic.com/media/a1862a_184e161a6c544d33b09a7598f6e5ce02~mv2.jpg/v1/crop/x_8,y_0,w_2296,h_494/fill/w_155,h_33,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/AD-Org%2520lett_edited.jpg)
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Ghosh, T.; Mukherji, A.; Kancharla, P. K.* “Influence of Anion-Binding Schreiner’s Thiourea on DMAP Salts: Synergistic Catalysis toward the Stereoselective Dehydrative Glycosylation from 2-Deoxyhemiacetals” J. Org. Chem. 2021, 86, 1253-1261. Link.
![TOC_edited.jpg](https://static.wixstatic.com/media/a1862a_995183e40d71490999d98320c81cc82d~mv2.jpg/v1/fill/w_123,h_33,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/TOC_edited.jpg)
2020
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Mukherji, A.; Kancharla, P. K.* “C−H···Anion Interactions Assisted Addition of Water to Glycals by Sterically Hindered 2,4,6-Tri-tert-butylpyridinium Hydrochloride” Org. Lett. 2020, 22, 2191–2195. Link.
![5-toc.tif](https://static.wixstatic.com/media/a1862a_b33dbed8b60d41fb9639246cfb3b5ea5~mv2.png/v1/fill/w_69,h_18,al_c,q_85,usm_0.66_1.00_0.01,blur_2,enc_auto/5-toc_tif.png)
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Halder, S.; Addanki, R. B.; Kancharla, P. K.* "Three Step Synthesis of L-Altrose from D-glucal derived Perlin Aldehyde" JICS, 2020, 97, 2, 243-250. Special Issue on Synthetic Carbohydrate Chemistry. Invited Article!! Link.
![TOC JICS.jpg](https://static.wixstatic.com/media/a1862a_fd57e5fffd694fff8f0b9eb81b6c5b6f~mv2.jpg/v1/fill/w_110,h_18,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/TOC%20JICS.jpg)
2019
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Ghosh, T.; Mukherji, A.; Kancharla, P. K.* “Open‐Close Strategy toward the Organocatalytic Generation of 2‐Deoxyribosyl Oxocarbenium Ions: Pyrrolidine‐Salt‐Catalyzed Synthesis of 2‐Deoxyribofuranosides” Eur. J. Org. Chem. 2019, 7488–7498. Link.
![ejoc201901465-toc.jpg](https://static.wixstatic.com/media/a1862a_5a3774b331214a95986e369e48962464~mv2.jpg/v1/fill/w_91,h_46,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/ejoc201901465-toc.jpg)
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Pawar, N. J.; Lei, W.; Higo, T.; Bhattacharya, C.; Kancharla, P. K.; Zhang, F.; Baryal, K.; Huo, C-X.; Liu, J.; Linhardt, R. J.; Huang, X.; Hsieh-Wilson, L. C.; “Expedient Synthesis of Core Disaccharide Building Blocks from Natural Polysaccharides for Heparan Sulfate Oligosaccharide Assembly” Angew Chem. Int. Ed. 2019, 58, 18577-18583. Link.
![anie201908805-toc-0001-m.jpg](https://static.wixstatic.com/media/a1862a_7a0abd098eb84dd6bb5aa2bb90975ecd~mv2.jpg/v1/fill/w_138,h_33,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/anie201908805-toc-0001-m.jpg)
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Ghosh, T.; Mukherji, A.; Kancharla, P. K.* “Sterically Hindered 2,4,6-Tri-tert-butylpyridinium Salts as Single Hydrogen Bond Donors for Highly Stereoselective Glycosylation Reactions of Glycals” Org. Lett. 2019, 21, 3490–3495. Link.
![2-toc.jpg](https://static.wixstatic.com/media/a1862a_0915b13440b644a3b3b8346d5f723da7~mv2.jpg/v1/fill/w_121,h_59,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/2-toc.jpg)
2018
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Ghosh, T.; Mukherji, A.; Srivastava, H. K.; Kancharla, P. K.* “Secondary amine salt catalyzed controlled activation of 2-deoxy sugar lactols towards alpha- selective dehydrative glycosylation” Org. Biomol. Chem. 2018, 16, 2870–2875. Link.
![TOC.jpg](https://static.wixstatic.com/media/a1862a_4beefad8d1674ecca7ebc22ef3527a47~mv2.jpg/v1/fill/w_108,h_37,al_c,q_80,usm_0.66_1.00_0.01,blur_2,enc_auto/TOC.jpg)
Before 2015
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Kancharla, P. K.; Takayuki Kato; David Crich, “Probing the Influence of Protecting Groups on the Anomeric Equilibrium in Sialic Acid Glycosides with the Persistent Radical Effect” J. Am. Chem. Soc., 2014, 136 (14), 5472-5480.
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Pavan K. Kancharla; David Crich, "Influence of Side Chain Conformation and Configuration on Glycosyl Donor Reactivity and Selectivity as Illustrated by Sialic Acid Donors Epimeric at the 7-Position" J. Am. Chem. Soc., 2013, 135 (50), 18999-19007.
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Rashmi Roy; Pavan K. Kancharla; Y. Suman Reddy; Anita Brar; Y. D. Vankar, "Synthesis of isofagomine and some new azasugars as glycosidase inhibitors from D-mannitol derived nitroolefins" Tetrahedron: Asymmetry 2013, 24, 1502-1513.
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Suresh Dharuman; Preeti Gupta; Pavan K. Kancharla; Y. D. Vankar, "Synthesis of 2-Nitroglycals from Glycals Using the Tetrabutyl ammonium Nitrate-Trifluoroacetic Anhydride-Triethylamine Reagent System and Base-Catalyzed Ferrier Rearrangement of Acetylated 2-Nitroglycals" J. Org. Chem. 2013, 78(17), 8442-8450.
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Pavan K. Kancharla; Chandrasekhar Navuluri; David Crich, "Dissecting the Influence of Oxazolidinones and Cyclic Carbonate Groups in Sialic Acid Chemistry" Angew. Chem. Int. Ed. 2012, 51, 11105-11109.
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Y. Suman Reddy; Pavan K. Kancharla; Rashmi Roy; Y. D. Vankar, "Aza-Claisen rearrangement of 2-C-hydroxymethyl glycals as a versatile strategy towards isofagomine and related biologically important azasugars" Org. & Biomol. Chem. 2012, 10, 2760-2773.
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Pavan K. Kancharla; Y. Suman Reddy; Suresh Dharuman; Y. D. Vankar, "A New Reagent System for the preparation of Nitro Olefins and Nitro Acetamides" J. Org. Chem. 2011, 76(14), 5832-5837.
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Pavan K. Kancharla; Y. D. Vankar "Chemistry of 2-nitroglycals: A One-Pot Three Component Stereoselective Approach Towards 2-C-Branched O-Galatcosides" J. Org Chem. 2010, 75, 8457-864.
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Pavan K. Kancharla; Venkata Ramana Doddi; Hariprasad Kokatla; Y. D. Vankar, "A concise route to (?)-shikimic acid and (?)-5-epi-shikimic acid, and their enantiomers via Barbier reaction and ring-closing metathesis" Tet. Lett. 2009, 50, 6951-6954.
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Hariprasad Kokatla; Rima Lahiri; Pavan K. Kancharla; Venkata Ramana Doddi; Y. D. Vankar, "Synthesis of (?) Deoxoprosophylline, (+)-2-epi-Deoxoprosopinine, and (2R,3R)- and (2R,3S)-3-Hydroxy pipecolic Acids from D-Glycals" J. Org. Chem. 2010, 75, 4608-4611.
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Venkata Ramana Doddi; Pavan K. Kancharla; Y. Suman Reddy; Y. D. Vankar; "Synthesis of fused pyran-carbahexopyranoses as glycosidase inhibitors" Carb. Res. 2009, 344, 606-612.
Book Chapters
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"2H-2-hydroxy-1,3,2-benzodithiazole 1,1,3,3-tetraoxide." Electronic Encyclopedia of Reagents for Organic Synthesis, ed. L. A. Paquette, John Wiley & Sons. Ltd. 2013, Pavan K. Kancharla
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"(2S)-N-(2,3,4,5,6-pentafluorophenyl)-2-pyrrolidinecarboxamide." Electronic Encyclo-pedia of Reagents for Organic Synthesis, ed. L. A. Paquette, John Wiley & Sons. Ltd. 2013, Pavan K. Kancharla.